MotoGP Valencia 2021 akan dimulai pukul 17.00 untuk kelas Moto3.
Adapun kelas premier akan dimulai pada pukul 20.00 dan disiarkan secara langsung di Trans7.
Berikut starting grid MotoGP Valencia 2021, Minggu (14/11/2021).
| POS. | PEMBALAP | TIM |
| 1 | Jorge Martin | Pramac Ducati (GP21)* |
| 2 | Francesco Bagnaia | Ducati Team (GP21) |
| 3 | Jack Miller | Ducati Team (GP21) |
| 4 | Joan Mir | Suzuki Ecstar (GSX-RR) |
| 5 | Johann Zarco | Pramac Ducati (GP21) |
| 6 | Alex Rins | Suzuki Ecstar (GSX-RR) |
| 7 | Brad Binder | Red Bull KTM (RC16) |
| 8 | Fabio Quartararo | Monster Yamaha (YZR-M1) |
| 9 | Takaaki Nakagami | LCR Honda (RC213V) |
| 10 | Valentino Rossi | Petronas Yamaha (YZR-M1) |
| 11 | Franco Morbidelli | Monster Yamaha (YZR-M1) |
| 12 | Aleix Espargaro | Aprilia Gresini (RS-GP) |
| 13 | Andrea Dovizioso | Petronas Yamaha (YZR-M1) |
| 14 | Maverick Viñales | Aprilia Gresini (RS-GP) |
| 15 | Iker Lecuona | KTM Tech3 (RC16) |
| 16 | Danilo Petrucci | KTM Tech3 (RC16) |
| 17 | Luca Marini | Sky VR46 Avintia Ducati (GP19)* |
| 18 | Enea Bastianini | Avintia Ducati (GP19)* |
| 19 | Alex Marquez | LCR Honda (RC213V) |
| 20 | Miguel Oliveira | Red Bull KTM (RC16) |