Berikut hasil kualifikasi MotoGP Valencia 2020, Sabtu (14/11/2020).
| POS | PEMBALAP | NEGARA | TIM | WAKTU/GAP |
| 1 | Franco Morbidelli | ITA | Petronas Yamaha (YZR-M1) | 1'30.191s |
| 2 | Jack Miller | AUS | Pramac Ducati (GP20) | +0.096s |
| 3 | Takaaki Nakagami | JPN | LCR Honda (RC213V) | +0.222s |
| 4 | Johann Zarco | FRA | Reale Avintia (GP19) | +0.329s |
| 5 | Pol Espargaro | SPA | Red Bull KTM (RC16) | +0.362s |
| 6 | Maverick Viñales | SPA | Monster Yamaha (YZR-M1) | +0.454s |
| 7 | Aleix Espargaro | SPA | Aprilia Gresini (RS-GP) | +0.466s |
| 8 | Francesco Bagnaia | ITA | Pramac Ducati (GP20) | +0.480s |
| 9 | Brad Binder | RSA | Red Bull KTM (RC16) | +0.546s |
| 10 | Miguel Oliveira | POR | Red Bull KTM Tech3 (RC16) | +0.590s |
| 11 | Fabio Quartararo | FRA | Petronas Yamaha (YZR-M1) | +0.673s |
| 12 | Joan Mir | SPA | Suzuki Ecstar (GSX-RR) | +0.797s |
| 13 | Cal Crutchlow | GBR | LCR Honda (RC213V) | 1'31.159s |
| 14 | Alex Rins | SPA | Suzuki Ecstar (GSX-RR) | 1'31.594s |
| 15 | Danilo Petrucci | ITA | Ducati Team (GP20) | 1'31.601s |
| 16 | Valentino Rossi | ITA | Monster Yamaha (YZR-M1) | 1'31.604s |
| 17 | Andrea Dovizioso | ITA | Ducati Team (GP20) | 1'31.606s |
| 18 | Stefan Bradl | GER | Repsol Honda (RC213V) | 1'31.831s |
| 19 | Tito Rabat | SPA | Reale Avintia (GP19) | 1'32.063s |
| 20 | Alex Marquez | SPA | Repsol Honda (RC213V) | 1'32.205s |
| 21 | Lorenzo Savadori | ITA | Aprilia Gresini (RS-GP) | 1'32.237s |